Role of citric acid in selective flotation of limonite from quartz

The effects of Fe 3+ and citric acid on the flotation behavior of both limonite and quartz and their separation were evaluated at pH 9.5 by using batch flotation tests, and the interaction mechanisms were investigated by solution chemistry, zeta potential measurements, infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), and ...

Diamine flotation of quartz

The flotation of Quartz was studied as a function of pH when using N-alkyl-1, 3 diaminopropanes and n-dodecylamine as collectors. The alkyl chains of the diamines were 8, 12 and 16 carbons in length.

Flotation of quartz particles assisted by nanobubbles

The quartz particle flotation assisted by nanobubbles (200–720 nm) was investigated. The nanobubbles increased the contact angle at the quartz/water interface. The …

Amine-coated nanobubbles-assisted flotation of fine and coarse quartz

True flotation recoveries with varying amine/g quartz, where the collector-frother amine may be amine-coated NBs alone or assisted by NBs generated in pure water, were compared with blank tests, in the absence of NBs. The flotation study evaluated size-to-size fractions from fine (−20 µm) to coarse (up to 150 µm) particles and their mixtures.

The application of a novel amine collector, 1

Quartz is commonly found alongside apatite as one of the main gangue minerals [10].Quartz differs from apatite in two key aspects: the absence of active sites, specifically referring to metal ions, on its surface and the higher electronegativity of its surface [11], [12], [13].Utilizing anionic collectors like fatty acids allows for the successful direct flotation …

Feldspar flotation as a quartz-purification method in …

Our flotation cell is built of borosilicate glass, holds up to 90 g of sample, and achieves quartz and feldspar separation in ≤2 h. The procedure uses air bubbles to which the …

Flotation separation of quartz from magnesite using

Meanwhile, the quartz grade in concentrate slightly decreased from 2.10% to 1.23% over the whole range of CMC dosage, suggesting that the quartz flotation induced by the DDA was barely affected by the presence of CMC. Fig. 5 Flotation behavior of mixed binary ore as function of CMC (MW of 90000 and DS of 0.7) concentration at pH 8.4 and DDA ...

Effect of surface roughness on the flotation separation

Froth flotation is a widely applied method to improve the quality and reduces impurity of concentrates depending on the significant difference in their surface physical and chemical properties [1], [2].During flotation, it is expected that a kind of mineral adheres to air bubbles and floats upward into the froth layer, and other minerals remain in the pulp as sink …

Application of ionic liquids as novel collectors with

Application of quaternary ammonium based ionic liquids as a novel flotation collector with low- viscosity of quartz has been investigated. The flotation behavior, performance and surface properties of quartz flotation with mono-2-ethylhexyl (2-Ethylhexyl)phosphonate-dodecyl trimethyl ammonium (P507-N12111) as collector were studied by ...

The role of phosphate in inhibiting the activation of quartz flotation

However, in flotation, the pulp is a complex system containing many ions and compounds from minerals dissolution or flotation agents. Ca 2+, Mg 2+, Cu 2+, Pb 2+, Zn 2+, and Fe 3+ are the most common and inevitable cations in flotation solutions [6], [7], [8].The presence of these metal ions could facilitate the flotation of quartz, thereby worsening the flotation …

Effect of metal ions on the flotation separation of biotite from quartz …

Metal cations have great effects on the flotation of silicate minerals whereas the interaction mechanism is unclear. Single mineral flotation demonstrated that the recovery of biotite rose to 94.69% and 96.41%, and that of quartz declined to 1.21% and 2.01% after introducing small amounts of Ca 2+ and Mg 2+, respectively.Artificial mixed mineral tests indicated that Ca …

Investigations on selective flotation separation of quartz …

In the study, to improve the water solubility and separation performance of quartz and hematite, a new cationic collector, (2-(dodecylamino)-2-methyl-1-propanol) (DAMP), was synthesized by introducing hydroxyethyl into the nitrogen atoms of DDA, which is a new type amine collector in the reverse flotation separation of quartz from hematite. The ...

On the role of nanobubbles in particle–bubble

Accordingly, almost 95% P 2 O 5 recovery was reached at the first 1.5 min, 9% higher than the maximum flotation in the standard tests, at 4 min. Quartz conditioned with nanobubbles increased flotation recoveries by approximately 23% when compared to the standard test. In the first min, the recovery of the quartz particles was about twice that ...

Separation of hematite and quartz in a cationic collector flotation …

Search ScienceDirect. Journal of Molecular Liquids. Volume 410, 15 September 2024, 125643. Separation of hematite and quartz in a cationic collector flotation system using Pullulan as a greener depressant. ... But flotation results indicated that it is not the case, and the quartz flotation was not depressed, so it could be speculated that the ...

Tannin: An eco-friendly depressant for the green flotation separation

TA depressed more than 90% of hematite particles under these conditions and less than 8% of quartz particles. Mixture micro-flotation results also depicted that hematite could selectively separate from quartz, where only in one stage flotation, a concentrate with 66.6% Fe grade and 87.7% iron recovery could be achieved.

Non-HF collectorless flotation of quartz

Pure mineral flotation experiments have demonstrated that quartz can be floated without a collector, in solutions containing an inorganic acid (e.g. H2SO4) and sodium fluoride (NaF).

Interface adsorption mechanism of 5-nonyl

The micro-flotation test was carried out by using an XFGC flotation machine with a fixed speed of 1758 r/min and a flotation cell volume of 30 mL. Before conducting the test, 2.0 g of malachite or quartz (calcite) was pretreated in an ultrasonic bath for 3 min, after that, the samples were transferred into the flotation cell and the pH was ...

New perspectives in iron ore flotation: Use of

Search ScienceDirect. Minerals Engineering. Volume 170, 15 August 2021, 107004. ... Studies performed on the flotation of quartz with etheramines as collectors showed the efficient depression of iron oxides by starch molecules from …

Towards a new process for the flotation of quartz

Traditionally, HF has performed two functions in the production of high purity quartz concentrates: Firstly, it has been used to activate feldspar prior to its flotation by amine collectors – thus enabling the separation of feldspar and quartz at low pH where the zeta-potentials of the former remains negative while that of the latter becomes close to neutral (Buckenham and …

Differential adsorption of a high-performance collector

However, as the starch concentration increased to 5 mg/L, the quartz recovery decreased slightly by 1.73% and maintained a high value of over 96.10%. These results indicated that starch had a remarkable depression impact on the hematite flotation but hardly depressed the quartz flotation when using the collector DEOSA.

A novel decyl-salicyl hydroxamic acid flotation

The flotation results of malachite and quartz with DSHA, SHA, and SIBX are shown in Fig. 1. The effect of pH on the flotation recovery of malachite under 200 mg/L DSHA is given in Fig. 1 (a). This indicates that the flotation recovery of malachite increases at …

The role of depressant pectin in the flotation

The experiment can be categorized as either single-mineral flotation or mixed-mineral flotation (spodumene + quartz), where the mixed ores were mixed according to the 1:1 ratio of mineral quality. For the flotation experiment, mineral particles (2 g each time) and 48 ml of distilled water were taken, added to the flotation cell, and then ...

Utilization of crown ether as selective collector for the flotation …

In this work, 12 kinds of crown ethers were screened to obtain good spatial compatibility with pollucite surface through computational simulations, and then a series of studies were conducted to explore the potential of the crown ether (DB21C7) as a selective collector in the pollucite-feldspar-quartz flotation system, aiming to separate pollucite.

Separation and Purification Technology

Quartz is a common associated impurity in minerals. It has been widely studied due to its flotation. For instance, Savas [5] and Cao et al. [6] deduced that using metal ions as activator, the NaOL collector has similar performance to cationic flotation in the collection of quartz, and it has a higher selectivity.

The molecular structure effects of starches and starch

1. Introduction. As the principal input material in industries of steelmaking, coating and durable pigments, hematite is an oxidized iron mineral ore with a formula of Fe 2 O 3 (Pauliuk, Milford, Müller, & Allwood, 2013).The major gangue mineral is quartz in oxidized iron ore, and reverse flotation is the most common method to beneficiate iron ore containing silica …

A Comparative Study of Quartz and Potassium Feldspar …

This study demonstrates a high froth flotation separation selectivity between quartz and feldspar and that quartz can be readily floated in diluted HF solutions with several frothers. …

Analysis of quartz floatability using design of …

Tests of microflotation of quartz, in the size range -150 +75 µm, using factorial design of experiments, showed that etherdiamine leads to higher level of quartz floatability than ethermonoamine, favored by increase in collector …

Study on the influence of particle size on the flotation …

The pH of positive flotation test is 6, and the pH of reverse flotation test is 12 as the test conditions of mixed flotation. 2 g of kaolinite was mixed with quartz as flotation samples, and the Al/Si value of flotation samples was calculated to be 0.334 based on the contents of Al 2 O 3 and SiO 2 in the chemical composition of kaolinite and ...

Flotation of quartz particles assisted by nanobubbles

Experimental studies of flotation of quartz particles, under various conditions and cells (setups), are presented. Pure and well-characterized quartz samples were treated with a commercial alkyl ether monoamine as flotation collector with bubbles in various sizes: coarse bubbles (400–800 μm); nanobubbles (200–720 nm); and their mixtures.The nanobubbles were …

Application of a novel mixed anionic/cationic collector

Recently, the development of mixed anionic/cationic collectors in the flotation separation of lithium-containing ores has become a research focus [28], [29].The synergistic effect of mixed anionic/cationic collectors can improve the floatability of target minerals [30], [31], [32], and the flotation separation of lepidolite and quartz could be realized at neutral pH [16].

Reverse froth flotation separation of limonite and quartz …

Currently reverse flotation is one of the most common industrial beneficiation methods for separating limonite from gangue minerals (Shrimali et al., 2018, Deng et al., 2021).In this process, the iron ore remains in the flotation tank as a non-floating fraction, while the silicate minerals float up to form a froth layer with the help of attached bubbles.

Utilization of aromatic hydroxamates with different

The implementation of a high-performance collector represents a promising strategy for enhancing mineral recovery. In this study, the flotation performance of hydroxamic acid was firstly investigated by examining the flotation behavior of pyrochlore, calcite, feldspar, and quartz using aromatic hydroxamates (AHA), namely methyl benzohydroxamic acid (MBHA), ethyl …

Mixed surfactants with solubilization behaviors

This study designed a mixed surfactant with solubilization behavior for selective flotation separation of feldspar and quartz. By optimizing the compounding ratio and dosage of reagents, the optimal mixed surfactants, dodecylamine (DDA), sodium dodecyl sulfate (SDS), and dodecane with the concentrations of 1.75, 0.58, and 3.5 mmol/L, used in flotation separation of feldspar …

Effects of Interfacial Hydroxylation Microstructure …

Given the strong polarity of the quartz surface, it is easy to hydrate to form a hydroxylation layer, which makes it impossible to float quartz with sodium oleate (OL) used alone. An ideal flotation method for quartz is …

Flotation of quartz from quartz-feldspar mixtures by

Froth flotation is the selected method for the separation of quartz and feldspar. In the conventional process, feldspar is floated from quartz by using hydrofluoric acid (HF) as activator for the feldspar and a cationic collector (amine) at pH 2–3 (O'Meara, 1939).

International Journal of Mineral Processing

Flotation of quartz samples (composites) having wide particle size distribution and results in a mechanical cell validated the overall recovery enhancement of the fines. Fine particle capture …

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